STUDY ON THE SYNTHESIS OF UREA-HYDROGEN PEROXIDE AND APPLICATION FOR OXIDATION OF BENZYLIC ALCOHOLS UNDER MICROWAVE ACTIVATION

Authors

  • Thuy Trang Bui Military Academy of Logistics, Hanoi, Vietnam
  • Van Hoa Le Le Quy Don Technical University, Hanoi, Vietnam
  • Hai Thuong Cao Le Quy Don Technical University, Hanoi, Vietnam

DOI:

https://doi.org/10.56651/lqdtu.jst.v17.n03.350

Keywords:

Oxidation reaction, benzylic alcohols, benzoic derivatives, Urea-Hydrogen Peroxide

Abstract

The Urea-Hydrogen Peroxide complex was synthesized from urea, hydrogen peroxide by using microwave assisted method and characterized by FT-IR. This Urea-Hydrogen Peroxide complex could be employed as an oxidizing agent for metal-free oxidation reaction of benzylic alcohols to carboxylic acids corresponding. This oxidation protocol, carried out under alkaline-water in microwave oven in presence of iodine as a catalyst, was efficient and compatible with a range of benzylic alcohols to afford a direct access to benzoic derivatives in very good yields up to 95.4% and high selectivities.

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Published

2022-06-09

How to Cite

Bui, T. T., Le, V. H., & Cao, H. T. (2022). STUDY ON THE SYNTHESIS OF UREA-HYDROGEN PEROXIDE AND APPLICATION FOR OXIDATION OF BENZYLIC ALCOHOLS UNDER MICROWAVE ACTIVATION. Journal of Science and Technique, 17(03), 5 - 12. https://doi.org/10.56651/lqdtu.jst.v17.n03.350

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